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High-temperature corrosion : ウィキペディア英語版
High-temperature corrosion

High-temperature corrosion is a mechanism of corrosion that takes place in gas turbines, diesel engines, furnaces or other machinery coming in contact with hot gas containing certain contaminants. Fuel sometimes contains vanadium compounds or sulfates which can form compounds during combustion having a low melting point. These liquid melted salts are strongly corrosive for stainless steel and other alloys normally inert against the corrosion and high temperatures. Other high-temperature corrosions include high-temperature oxidation, sulfidation and carbonization.
==Sulfates==
Two types of sulfate-induced hot corrosion are generally distinguished: Type I takes place above the melting point of sodium sulfate and Type II occurs below the melting point of sodium sulfate but in the presence of small amounts of SO3.
In Type I the protective oxide scale is dissolved by the molten salt. Sulfur is released from the salt and diffuses into the metal substrate forming discrete grey/blue colored aluminum or chromium sulfides so that, after the salt layer has been removed, the steel cannot rebuilt a new protective oxide layer. Alkali sulfates are formed from sulfur trioxide and sodium-containing compounds. As the formation of vanadates is preferred, sulfates are formed only if the amount of alkali metals is higher than the corresponding amount of vanadium.〔
The same kind of attack has been observed for potassium and magnesium sulfate.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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